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Just to clarify: Berlin discovered that his SMTP server only permits outbound, unauthenticated mail to recipients in its own domain. He was using a test account outside of the server’s domain, that’s why it required authentication. When he changed the recipient, it worked fine.
The link that Boone provided sure enough shows you how to authenticate send mail requests in PHP. Looks pretty easy to do. I don’t know PHP but it looks very similar to Perl.